The importance of iron speciation (Fe+2/Fe+3) in determining mineral assemblages: an example from the high‐grade aluminous metapelites of southeastern Madagascar     

S. D. BOGER  R. W. WHITE  B. SCHULTE 《Journal of Metamorphic Geology》2012,30(9):997-1018

Metapelitic granulites from the Anosyen domain of southeastern Madagascar are exposed in three intercalated formations: the Amparihy, Bakika and Ihosy formations. Although mineralogically distinct from each other, the rocks from these formations show very similar bulk‐rock compositions when measured on a Fe_T basis. The preserved mineral assemblages thus do not reflect differences in the ratios of the main rock‐forming oxides (i.e. Al₂O₃:Fe_T:MgO), but instead reflect variations in the pre‐metamorphic oxidation state of the protolith rocks. These differences in oxidation state are manifested via differences in iron speciation – either Fe⁺² or Fe⁺³. The relatively reduced rocks of the Amparihy Formation preserve the assemblage bi–sp–sill–g–cd, which contrasts markedly with the mostly garnet and spinel‐absent bi–cd–sill–mt assemblages preserved in the strongly oxidized rocks of the Ihosy Formation. Compositionally intermediate rocks of the Bakika Formation are garnet bearing, but sillimanite‐absent, and contain the assemblage sp–g–cd–mag. Modelling of these rocks in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O system suggests that they evolved along a heating and cooling P–T path with only limited decompression accompanying cooling on the retrograde path. Peak temperatures and pressures of ～880–920 °C and 6–6.5 kbar are inferred for the majority of the Anosyen domain, with slightly lower peak temperatures (～840 °C) estimated in the extreme northwest of the area. The high‐temperature and relatively low‐pressure nature of metamorphism suggests high geothermal gradients existed during orogenesis, which in southern Madagascar is related to the amalgamation of Gondwana (580–520 Ma). Although metamorphic temperatures may have been augmented via thermal advection from the emplacement of the syn‐ to post‐tectonic Ambalavao suite, the high geothermal gradients nevertheless suggest thin and consequently hot lithosphere existed prior to orogenesis.  相似文献   

Cavity expansion analyses of crushable granular materials with state‐dependent dilatancy     

M. J. Jiang  Y. G. Sun 《国际地质力学数值与分析法杂志》2012,36(6):723-742

Crushability is one of the important behaviors of granular materials particularly under high stress states, and affects both the deformability and strength of the materials that are in essence associated with state‐dependent dilatancy. In this presentation, first, a new critical state model is proposed to take into account the three different modes of compressive deformation of crushable granular materials, i.e. particle rearrangement, particle crushing and pseudo‐elastic deformation. Second, the governing equations for cavity expansion in crushable granulates are introduced, in which the state‐dependent dilatancy as well as the bounding surface plasticity model are used. Then, the procedure to obtain semi‐analytical solutions to cavity expansion in the material is described in detail, in which a commercial differential equation solver is employed. Finally, cavity expansion analyses are carried out on Toyoura sand, a well‐documented granular material, to demonstrate the effects of crushability and state‐dependent dilatancy. The study shows that particle crushing does occur at both high stress and critical states and affects the stress fields and the deformation behavior of the material surrounding the cavity in association with state‐dependent dilatancy. This leads to conclusion that particle crushing and state‐dependent dilatancy have to be taken into account when cavity expansion theory is used to interpret cone penetration tests and pressuremeter tests. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Numerical local analysis of relevant internal variables for constitutive modelling of granular materials     

Yuhanis Yunus  Eric Vincens  Bernard Cambou 《国际地质力学数值与分析法杂志》2010,34(11):1101-1123

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Using modified state surface approach to select parameter values in the Barcelona basic model     

Xiong Zhang  Ming Xiao 《国际地质力学数值与分析法杂志》2013,37(12):1847-1866

The Barcelona basic model (BBM) successfully explained many key features of unsaturated soils and received extensive acceptance. It is also one of the few elastoplastic constitutive models for unsaturated soils that have been implemented within finite element codes and applied to the analysis of real boundary value problems. The BBM was proposed in incremental forms according to theories of soil plasticity in which individual aspects of the isotropic virgin behavior are controlled by multiple parameters, whereas at the same time, a single parameter controls more than one aspect of soil behavior. Although a variety of methods have been recently developed for calibrating model parameters for elastoplastic soil models, at present, there are no well‐established, simple, and objective methods for selecting parameter values in the BBM from laboratory tests. This has been one of the major obstacles to the dissemination of this constitutive model beyond the research context. This article presents an optimization approach especially developed for simple and objective identification of material parameters in the BBM. This is achieved by combining a modified state surface approach, recently proposed to model the elastoplastic behavior of unsaturated soils under isotropic stress conditions, with the Newton or quasi‐Newton method to simultaneously determine the five parameters governing isotropic virgin behavior in the BBM. The comparison between results using the proposed method and an existing method for the same laboratory tests was discussed from which the simplicity and objectivity of the proposed method were evaluated. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Temporal electronic structure of non-resonant Raman excited virtual state of P-nitroaniline by 514 nm excitation via bond polarisabilities     

王培杰  方炎  吴国祯 《海洋学报(英文版)》2010,29(11)

We have studied the temporal bond polarisabilities of para-nitroaniline from the Raman intensities by the algorithm proposed by Wu et al. in 1987 (Tian B, Wu G, Liu G 1987 J. Chem. Phys. 87 7300). The bond polarisabilities provide much information concerning the electronic structure of the non-resonant Raman excited virtual state. At the initial moment by the 514.5 nm excitation, the tendency of the excited electrons (mapped out by the bond polarisabilities) is to spread to the molecular periphery, and the electronic structure of the Raman virtual state is close to the pseudo-quinonoidic state. When the final stage of relaxation is approached, the bond polarisabilities of those peripheral bonds relax faster than those closer to the molecular core, the phenyl ring. The molecule is in the benzenoidic form as demonstrated by the bond polarisabilities after relaxation.  相似文献   

代理协助P2P-VoD系统中基于缓存状态的服务节点选择策略   总被引：1，自引：0，他引：1  

唐瑞春  徐仕儒  魏青磊 《中国海洋大学学报(自然科学版)》2010,40(4)

研究P2P-VoD系统中提供流媒体服务的公平性问题,提出基于缓存状态的DRPS(Data Receiving Peers as Suppliers)服务节点选择策略,并设计基于DRPS的预分配调度算法PSA(Preassign Scheduling Algorithm)。首先根据缓存状态将节点分类,再结合节点的可用带宽和可用概率进行排序,优先从RS(Receiving Set)节点类中选择服务提供者,最后由客户端执行PSA算法。仿真实例表明该策略的有效性。  相似文献   

Enhanced identification of a hydrologic model using streamflow and satellite water storage data: A multicriteria sensitivity analysis and optimization approach   总被引：1，自引：0，他引：1       下载免费PDF全文

Fuad Yassin  Saman Razavi  Howard Wheater  Gonzalo Sapriza‐Azuri  Bruce Davison  Alain Pietroniro 《水文研究》2017,31(19):3320-3333

Hydrologic model development and calibration have continued in most cases to focus only on accurately reproducing streamflows. However, complex models, for example, the so‐called physically based models, possess large degrees of freedom that, if not constrained properly, may lead to poor model performance when used for prediction. We argue that constraining a model to represent streamflow, which is an integrated resultant of many factors across the watershed, is necessary but by no means sufficient to develop a high‐fidelity model. To address this problem, we develop a framework to utilize the Gravity Recovery and Climate Experiment's (GRACE) total water storage anomaly data as a supplement to streamflows for model calibration, in a multiobjective setting. The VARS method (Variogram Analysis of Response Surfaces) for global sensitivity analysis is used to understand the model behaviour with respect to streamflow and GRACE data, and the BORG multiobjective optimization method is applied for model calibration. Two subbasins of the Saskatchewan River Basin in Western Canada are used as a case study. Results show that the developed framework is superior to the conventional approach of calibration only to streamflows, even when multiple streamflow‐based error functions are simultaneously minimized. It is shown that a range of (possibly false) system trajectories in state variable space can lead to similar (acceptable) model responses. This observation has significant implications for land‐surface and hydrologic model development and, if not addressed properly, may undermine the credibility of the model in prediction. The framework effectively constrains the model behaviour (by constraining posterior parameter space) and results in more credible representation of hydrology across the watershed.  相似文献   

Generalized plasticity state parameter‐based model for saturated and unsaturated soils. Part II: Unsaturated soil modeling     

Diego Manzanal  Manuel Pastor  José Antonio Fernández Merodo 《国际地质力学数值与分析法杂志》2011,35(18):1899-1917

The aim of this paper is to extend the generalized plasticity state parameter‐based model presented in part 1 to reproduce the hydro‐mechanical behavior of unsaturated soils. The proposed model is based on two pairs of stress–strain variables and a suitable hardening law taking into account the bonding—debonding effect of suction and degree of saturation. A generalized state parameter for unsaturated state is proposed to reproduce soil behavior using a single set of material parameters. Generalized plasticity gives a suitable framework to reproduce not only monotonic stress path but also cyclic behavior. The hydraulic hysteresis during a drying—wetting cycle and the void ratio effect on the hydraulic behavior is introduced. Comparison between model simulations and a series of experimental data available, both cohesive and granular, are given to illustrate the accuracy of the enhanced generalized plasticity equation. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

移动状态边界面法在黏性土不排水蠕变孔压分析中的应用     

高彦斌 《岩土力学》2018,39(11):4176-4182

在黏性土的各种流变现象的数学模拟研究中,不排水蠕变孔压方程几乎是空白。基于临界状态土力学理论,采用与时间相关的移动状态边界面法,给出了适用于正常固结黏性土的不依赖状态边界面具体形态的不排水蠕变孔压公式。正常固结黏性土的不排水蠕变孔压可以看作是体积蠕变势和剪应力水平增大造成的剪缩这两种作用的结果,前者与参数 有关（ 为次压缩指数, 为压缩指数）,后者则与状态边界面的具体形态有关。在此基础上进一步给出了可方便用于试验数据分析的双对数和单对数形式的两个公式。以修正剑桥模型椭圆形状态边界面为例,分析了双对数和单对数坐标系下蠕变孔压曲线的斜率m和m′与土的流变参数 的关系。采用提出的方法,很好地预测了Walkers给出的Leda clay黏土的蠕变孔压系数,并基于以上两种作用解释了Leda clay黏土的蠕变孔压形成的机制。  相似文献   

土-膨润土隔离墙应力状态与固结行为的现场试验研究     

童星  李育超  柯瀚  文一多  潘倩 《岩土力学》2018,39(6):2131-2138

土-膨润土竖向隔离墙被广泛应用于污染场地治理,其服役性能受应力状态和固结变形影响较大。通过建造两段不同尺寸的土-膨润土隔离墙试验段,并利用土压力盒、孔压计、测斜管等分别对墙体现场应力状态和变形进行了为期15个月的监测,获得了土-膨润土隔离墙固结行为的基本特征。监测结果表明：墙体主固结阶段需要数月;墙体固结变形以侧向变形为主;大部分深度内总应力在前1个月显著减小,并在随后基本保持稳定,有效应力随超孔压消散而不断增加;水平应变与最大水平有效应力均与墙深呈显著正相关;然而在主固结期间,墙体底部总应力和孔压均一直减小直至等于静水压力,有效应力始终很小。根据实测墙体变形及应力分布的特点,指出在相邻土体中可能形成滑动楔形体,对填料产生整体挤压,从而对隔离墙的现场固结行为特征作出了合理解释。最后,针对土-膨润土隔离墙的设计施工提出了相关建议。  相似文献